Process parameters influence on zone refining and thermodynamics analysis of 1,2-diphenylethane

Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature. The effect of varied zone size, temperature difference between the melt and ambient frozen environment, number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining. The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%-0.2% than that with constant zone size. The product purity increases with temperature difference between the melt and ambient frozen environment. The appropriate temperature difference is adopted 50℃. The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%-0.43% than that with 1 molten zone. In addition, the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined.     

Novel nanometer alumina-silica insulation board with ultra-low thermal conductivity

Advanced nano-porous super thermal insulation materials are widely used in spacecraft, soler-thermal shielding, heat exchangers, photocatalytic carriers due to their low thermal conductivity. In this work, adopting dry preparation technology, nano-Al₂O₃, nano-SiO₂, SiC and glass fibers as raw materials, novel nanometer alumina-silica insulation board (NAIB) were prepared. The preparation process was simple, safe, and reliable. In addition, the NAIB exhibited a high porosity (91.3–92.3%), small pore size (39.83–44.15 nm), low bulk density (0.22–0.26 g/cm³), better volumetric stability, and low thermal conductivity (0.031–0.050 W/(m·K) (200–800 °C)), respectively. The as-prepared NAIB could render them suitable for application as high-temperature thermal insulation materials.     

Effects of particle size distribution and sintering temperature on properties of alumina mold material prepared by stereolithography

Alumina mold materials prepared by stereolithography usually have considerable sintering shrinkage, and their properties related to casting have been rarely studied. In this study, alumina molds materials were prepared by stereolithography, and the effects of particle size distribution and sintering temperature on the properties of the materials were investigated. Results show that the viscosity of the slurries decreases as the fraction of fine powder increases, and the particle size distribution affects the curing behaviors slightly. Sintering shrinkage increases as the fraction of fine powder or the sintering temperature increases. Although lower sintering shrinkage can be achieved by sintering at 1350 °C or 1450 °C, the mold materials sintered at lower temperatures would continue to shrink under the service temperature of 1550 °C, and thus 1550 °C is determined as the optimal sintering temperature. As the fraction of fine powder increases, the creep resistance first increases and then decreases, and specimens prepared with 0.1 fraction of fine powder exhibit the best creep resistance with the droop distance of 4.44 ± 0.45 mm. Specimens prepared with 0.1 fraction of fine powder and sintered at 1550 °C exhibit linear shrinkage of 6.36% along the X/Y direction and 11.39% along the Z direction, and have a flexural strength of 78.15 ± 3.50 MPa and porosity of 30.12 ± 0.08%. The resulting material possesses relatively low sintering shrinkage, proper mechanical strength, porosity and high-temperature properties that meet the requirements for casting purposes.     

Effect of laver powder on textual,rheological properties and water distribution of squid (Dosidicus gigas) surimi gel

In order to ameliorate the gel quality of Dosidicus gigas surimi, the effects of laver powder on gel properties, rheological properties, and water-holding capacity (WHC) were investigated. Results indicated that the addition of laver powder could significantly increase the hardness, chewiness, and breaking force of surimi gels. However, the texture indexes and gel strength began to decline when additional amount exceeded 0.6%. Rheological results demonstrated that the addition of laver powder increased the storage modulus (G′) and viscosity of surimi, prolonged protein denaturation temperature in surimi gels. Moreover, the WHC of surimi gel was improved with the increase of laver powder. Further analyses in low-field nuclear magnetic resonance revealed that laver powder could shorten the transverse relaxation time, enhanced the combination with water, and altered the distribution of different water categories. The proportion of bound water and immobilized water reached its maximum and minimum at 0.6% of laver powder, respectively. Correlation analyses showed that WHC of surimi gel was negatively correlated well with the proportion of loose-bound water, but positively correlated with the strong-bound water and free water. In conclusion, the results supported that 0.6% was the optimal additional amount of laver powder for the squid-based surimi production based on the current ingredients of surimi products.     

Zone model predictive control for pressure management of water distribution network

In the water distribution network (WDN), although the water demand of the node is changing constantly, the water quantity and water pressure of the node need to be met at each moment. To realize energy saving and consumption reduction, it is proposed to control the nodal water head of WDN in an appropriate narrow range. The frequent large fluctuation of the water demand, which may lead the water pressure exceed the expected range, increases the difficulty of the zone control. To realize optimized WND control, a novel zone predictive control is proposed, where two switching cases are considered. The switching condition is whether there are feasible solutions to keep the pressure within the expected region over the prediction horizon. When the condition is satisfied, the controller minimizes the variation of inputs with constraints of pressure range for ensuring the tank level staying within the expected zone and obtaining optimal economic cost. When the current pressure is out of the expected region or the condition is not satisfied due to the large variation of water demand, a reference trajectory of outputs is introduced, which is combined with the inputs as an optimization variable, and the constraints of expected zone are moved from the output to the introduced reference trajectory. Through minimizing the distance between reference trajectory and output, the controller will keep the tank level from deviating too far from the expected zone and will drive the tank level rapidly into the expected zone once the tank level exceeds the expected range. An application of the proposed zone MPC to WDN in Shinan District of Shanghai is given to illustrate its effectiveness.     

东濮凹陷濮卫洼陷带沙一上亚段沉积相与储层分布特征研究

东濮凹陷濮卫洼陷带沙一上亚段,从沙一上3到沙一上1,水体逐渐变浅、退出本区,上2-3组发育以湖相为主的沉积体,上1组向以河流相为主的沉积体过渡;砂岩在每个组均有分布,上2-3主要为分布在文明寨地区、卫城构造北部的受断层控制在断层下降盘形成的远(近)岸浊积砂体,以及濮城构造北部的滩坝砂,上1为主要分布在文明寨地区、卫城构造及濮城构造南部的条带状河道砂体。     

阳泉矿区煤样不同应力状态下声发射特性分析

为探索原煤煤样的力学性能和不同应力状态下的声发射活动特性,对阳泉矿区新景矿、平舒矿主采煤层的煤样进行了单轴、三轴压缩和巴西劈裂的声发射试验,分析了2种煤样力学性能及不同加载过程的声发射活动规律。证明通过监测声发射(微震)活动分析煤样或煤岩体内部破坏状态是一种方便有效的手段。     

Beta-Binomial删除信道中的喷泉码文件传输协议

由于命名数据网络(NDN,Named-Data Networking)无环路、逐包、逐跳转发的特点,使得数据包回传成功率降低,而传统的TCP/IP协议中的ARQ和ACK机制对于多播会话不再适用.由于NDN中的传输信道可以等效为二进制删除信道,因此可以通过应用层编码来实现文件的可靠传输.传统的信道编码技术如卷积码、级联码和RS码等复杂度较高,而将NDN与低复杂度的喷泉码的结合可以实现分布式的存储架构,因而可通过喷泉编码在应用层协议中实现可靠的纠删机制,保证整体文件的传输可靠性.以往的研究一般是基于确定的删除概率信道模型,但是由于网络的异构性和信道噪声等因素影响,可能会造成信道丢包概率呈随机性分布.因此,本文在Beta-Binomial分布模型的前提下,根据贝叶斯统计的先验信息和中心极限定理,对随机概率下的纠删信道的文件可靠传输协议进行了数学建模和理论推导.仿真结果显示此模型更具有普适性,此传输协议可在信道状况未知的前提下从理论上求出最小发包数,减少冗余编码包,提高文件整体的投递成功率,在保证传输可靠性的同时有效提升协议传输效率.     

肉桂特色资源加工利用产业发展现状

肉桂是我国特色经济林树种，我国肉桂种植面积和年产量均居世界首位。我国肉桂主要分布在两广地区，其中广西为14.9万hm²，广东为8.9万hm²，两地面积占全国肉桂分布总面积的95%以上。肉桂既是著名的香料又是传统的名贵中药，具有极高的经济价值，发展肉桂产业对于促进农民增收、维护健康中国有着重要的意义。本研究综述了肉桂资源量、分布情况及主要利用部位，介绍肉桂主要产品（如桂皮，桂枝，肉桂粉及肉桂油）及加工技术现状、产品质量控制及其分析检测方法，分析了产业未来的发展趋势，并提出了产业发展的对策和措施：加强肉桂标准化示范基地建设，提高优质资源供给能力；提高肉桂加工利用技术水平，延长产业链；培育肉桂龙头企业，提高产品市场竞争力。为我国肉桂特色资源加工利用产业的可持续发展提供一定的思路。